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Physical
Properties for Supercritical Fluid-Aided Polymer Processing
Shigeki TAKISHIMA
Department of Chemical Engineering,Graduate School of Engineering, Hiroshima
University
Nippon Gomu Kyokaishi,(2004),77(10),336-342 General Review in Japanese
Abstract
Solubility, diffusivity
and viscosity in supercritical fluid and polymer systems are reviewed.
Supercritical fluids such as carbon dioxide dissolve in polymers at
high pressures and plasticize them. The increase in diffusivity and
the decrease in viscosity of polymers with dissolved supercritical
fluids are due to the plasticizing effect of supercritical fluids.
In this article general tendency, data source and theoretical calculation
methods of solubility, diffusivity and viscosity are presented for
supercritical carbon dioxide and nitrogen in polymers.
Keywords:
Supercritical fluid, Solubility, Diffusivity, Viscosity, Equation
of state
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