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Fundamentals and Mechanical Properties of PSA Tapes
6. Investigation of Mechanical Properties of PSAs by Using Retardation Spectrum
Yoshiaki URAHAMA
Project Researcher, Venture Business Laboratory, Yamagata University
Nippon Gomu Kyokaishi,(2004),77(9),324-329 General Review in Japanese
Abstract
A pressure sensitive adhesive is a lightly cross-linked polymer with the
capability of 1,000-2,000% of large deformation.
The behavior completely differs from the behavior of linear viscoelasticity.
Numerical differentiation of the large-deformation creep data was carried out,
and the retardation spectrum was obtained.
As a result, the followings became clear.
(1) It became clear that the influence of the cross-linking degree of
PSA appears in a long-term region, while theeffect of chemical composition
of a PSA appears in a short-term region.
(2) In polymer/tackifier PSA system, it became clear that the short-term
region of the retardation spectrum shape depends on the chemical structure of
the tackifier, while the long-term region of it depends on the softening point.
Keywords:
Pressure sensitive adhesive, Acrylic polymer, Block polymer, Tackifier, Retardation spectrum, Creep
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